High young modulus vitrimers
WebSep 1, 2024 · The nature of the bond exchange enables vitrimers to retain their modulus upon heating 32,33. If we consider the boric esters as the treated healing agent, their length scale approaches ~1 Å. Web2 days ago · It was revealed that the epoxy vitrimers exhibited outstanding mechanical properties, while the storage modulus (E′) at 25 °C was determined to be ∼1.3 GPa and the tensile strength was up to 60.7 ± 11.1 MPa (Fig. S1, ... High-performance vitrimers from commodity thermoplastics through dioxaborolane metathesis. Science, 356 (6333) …
High young modulus vitrimers
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WebNov 25, 2024 · It can be seen that high-density vitrimers (ρ ≥ 2.0) exhibit a relatively steep growth of τ upon supercooling, indicative of fragile glass formation, while intermediate … WebJan 5, 2024 · It remains a challenge to use a simple approach to fabricate a multi-shape memory material with high mechanical performances. Here, we report a triple crosslinking …
WebDec 19, 2024 · Young's modulus (MPa) Toughness (MJ m −3) Healing conditions Healing efficiency (%) ... plastics being difficult to recycle. In order to solve this problem, researchers have developed HTPB-based PU vitrimers with disulfide bonds ... and extremely high Young's modulus (81.8 MPa) due to the abundant interfacial hydrogen bonds between … Thermoplastics are easy to process, but corrode easily by chemicals and mechanical stress, while the opposite is true of thermosets. These differences arise from how the polymer chains are held together. Historically, thermoset polymer systems that were processable by virtue of topology changes within the covalent networks as mediated by bond exchange reactions were also developed by J…
WebJan 5, 2024 · Epoxy vitrimers with 10 phr FEHBP exhibited high tensile strength (126.4 MPa), usable Tg (94 °C), fast stress relaxation (a relaxation time of 45 s at 140 °C) and a … WebJul 15, 2024 · Meanwhile, the tensile stress and Young modulus of the vitrimer are higher than 70 MPa and 2600 MPa, demonstrating a superior mechanical property compared …
WebRosin side chain type catalyst-free vitrimers with high cross-link density, mechanical strength, and thermal stability: Yunpeng Shen 1, Weishan Tang 1, Jinyang Li 1, Zhijun Ke 1, Lirong Liao 1, Peng Yang 1, Yuntao Lu 1, Xiaoping Rao 1, 2 (): 1.College of Chemical Engineering, Huaqiao University, Xiamen 361021, China 2.Academy of Advanced Carbon …
WebAug 10, 2024 · In the DHEBA-enriched network, the modulus drop associated with the alpha transition occurs at higher temperatures and more steeply than in the pristine network, demonstrating better homogeneity... citizen gateway loginWebJul 25, 2024 · These vitrimers allow for flexibile modulation of their network structures and thus show a range of intriguing properties including high stretchability, flexible transition from elasticity to plasticity, strong strain rate dependence, and solid-liquid performance. dichotomous fish keyWebIt is seen from Fig. 3a–c that the increase of heating time from 20 min to 2 h results in a gradual increase of rubbery modulus from ∼4.7 MPa to ∼10 MPa, which suggests that the voids in the vitrimer blends are gradually closed and more polymer chains are connected between particle interfaces. 15,35 Above the heating time of 2 h, the rubbery … dichotomous framingWebJul 7, 2024 · Swelling and degradation of VMP and VHP bio-based imine epoxy vitrimers The swelling experiment was conducted by immersing the cross-linked epoxy resins in different solvents. After 24 h, the swollen samples were taken out, the surface solvent was wiped dry and weighed. Calculated the swelling ratio (SR) according to formula (1) [ 47 ]. dichotomous geneticsWebAug 26, 2024 · The plateau modulus at high frequency increases as a function of temperature, as expected for a conserved network topology. When plotted against inverse … dichotomous functionWebJan 13, 2024 · With the inclusion of 20 wt % acrylamide, the average tensile strength and Young's modulus are up to 40.1 and 871 MPa, which increased by about 4.4 and 3.85 times, respectively. The network rearrangement of cross-linked vitrimers can be achieved through the dynamic ester exchange reactions with gradual disappearance of hydrogen bonds at ... dichotomous hyphaeWebMar 21, 2024 · Vitrimers have been investigated in the past decade for their promise as recyclable, reprocessable, and self-healing materials. In this Viewpoint, we focus on some of the key open questions that remain regarding how the molecular-scale chemistry impacts macroscopic physical chemistry. citizen gas utility district